Development and synthesis of novel representatives of polyazido-substituted N-(alkoxymethyl)nitramines

α,ω-Dichloro-β-nitrazaalkanes on treatment with (poly)halo alcohols undergo chemoselective substitution in the activated N-chloromethyl moiety. The thus prepared polyhalo derivatives are converted into the corresponding polyazido compounds which can be the promising energetic plasticizers and monomers.