V. S. Zimarev, I. V. Chuchelkin, K. N. Gavrilov, I. A. Zamilatskov, V. A. Tafeenko, B. V. Lokshin, N. S. Goulioukina, “Neutral dinuclear palladium(II) complex containing chiral P,S-bridging diamidophosphite-thioether ligands”, Mendeleev Commun., 34:2 (2024), 195

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Mendeleev Communications, 2024, Volume 34, Issue 2, Pages 195–197
DOI: https://doi.org/10.1016/j.mencom.2024.02.011 (Mi mendc80)

This article is cited in 1 scientific paper (total in 1 paper)

Communications

Neutral dinuclear palladium(II) complex containing chiral P,S-bridging diamidophosphite-thioether ligands

V. S. Zimarev^ab, I. V. Chuchelkin^b, K. N. Gavrilov^b, I. A. Zamilatskov^c, V. A. Tafeenko^a, B. V. Lokshin^d, N. S. Goulioukina^abc

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Department of Chemistry, S.A. Esenin Ryazan State University, Ryazan, Russian Federation
^c A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
^d A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Full-text PDF (468 kB) Citations (1) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2024.02.011

Graphic abstract: Neutral dinuclear palladium(II) complex containing chiral <i>P</i>,<i>S</i>-bridging diamidophosphite-thioether ligands

Abstract: An unusual neutral dinuclear palladium(II) complex with two head-to-head orientated μ-P,S-bridging ligands was obtained by the reaction of Pd(MeCN)₂ Cl₂ with (1R,5R)-3-(4-phenylthiobutoxy)-2,4-diphenyl-2,4-diaza-3-phospha-bicyclo[3.4.0]nonane. The dimeric structure of the complex in the solid state and in solution was thoroughly confirmed using appropriate analytical techniques: single crystal X-ray diffraction analysis, HRMS, FTIR and NMR spectroscopy.

Keywords: dinuclear complexes, palladium(II) complexes, P,S-bidentate ligands, 1,3,2-diazaphospholidines, X-ray crystal structures.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.0 Mb)

Citation: V. S. Zimarev, I. V. Chuchelkin, K. N. Gavrilov, I. A. Zamilatskov, V. A. Tafeenko, B. V. Lokshin, N. S. Goulioukina, “Neutral dinuclear palladium(II) complex containing chiral P,S-bridging diamidophosphite-thioether ligands”, Mendeleev Commun., 34:2 (2024), 195–197

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https://www.mathnet.ru/eng/mendc/v34/i2/p195

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