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Mendeleev Communications, 2021, Volume 31, Issue 1, Pages 17–19
DOI: https://doi.org/10.1016/j.mencom.2021.01.004
(Mi mendc820)
 

This article is cited in 5 scientific papers (total in 5 papers)

Communications

Metastable ionic cubic structure I clathrate hydrate formed with tetra-n-butylammonium bromide

A. S. Stoporevabc, A. G. Kiiamovd, M. A. Varfolomeeva, T. V. Rodionovab, A. Yu. Manakovbc

a Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation
b A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
c Department of Natural Sciences, Novosibirsk State University, Novosibirsk, Russian Federation
d Institute of Physics, Kazan Federal University, Kazan, Russian Federation
Full-text PDF (301 kB) Citations (5)
Abstract: Ionic clathrate hydrates formed from aqueous solutions of tetra-n-butylammonium bromide in the course of rapid cooling (30Kmin−1) to −35°C have been examined. An earlier unknown metastable hydrate of cubic structure I was obtained from the solutions with concentrations from 3.2 to 4.8 mol%.
Keywords: ionic clathrate hydrate, tetra-n-butylammonium bromide, cubic structure I, metastable state, powder X-ray diffraction.
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Document Type: Article
Language: English


Citation: A. S. Stoporev, A. G. Kiiamov, M. A. Varfolomeev, T. V. Rodionova, A. Yu. Manakov, “Metastable ionic cubic structure I clathrate hydrate formed with tetra-n-butylammonium bromide”, Mendeleev Commun., 31:1 (2021), 17–19
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  • This publication is cited in the following 5 articles:
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