S. E. Boganov, V. M. Promyslov, P. G. Shangin, M. A. Syroeshkin, M. P. Egorov, “Interaction of SiCl2 with CO2 in Ar matrices”, Mendeleev Commun., 31:2 (2021), 149

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Mendeleev Communications, 2021, Volume 31, Issue 2, Pages 149–153
DOI: https://doi.org/10.1016/j.mencom.2021.03.002 (Mi mendc862)

This article is cited in 5 scientific papers (total in 5 papers)

Communications

Interaction of SiCl₂ with CO₂ in Ar matrices

S. E. Boganov, V. M. Promyslov, P. G. Shangin, M. A. Syroeshkin, M. P. Egorov

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Full-text PDF (482 kB) Citations (5) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2021.03.002

Graphic abstract: Interaction of SiCl<sub>2</sub> with CO<sub>2</sub> in Ar matrices

Abstract: A 1: 1 photostable complex between dichlorosilylene and CO₂ was detected using matrix-isolation FTIR spectroscopy. The photostability can be attributed to the existence of photochemical equilibria between this complex and products of its isomerization, first of all, a complex of dichlorosilanone with CO, which are strongly shifted to the complex. A detailed computational study of the potential energy surface of the SiCl₂+CO₂ system was carried out.

Keywords: dichlorosilylene, dichlorosilanone, carbon dioxide, carbon monoxide, donor–acceptor complexes, matrix isolation, FTIR spectroscopy, quantum chemical calculations.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(946.0 Kb)

Citation: S. E. Boganov, V. M. Promyslov, P. G. Shangin, M. A. Syroeshkin, M. P. Egorov, “Interaction of SiCl₂ with CO₂ in Ar matrices”, Mendeleev Commun., 31:2 (2021), 149–153

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https://www.mathnet.ru/eng/mendc/v31/i2/p149

This publication is cited in the following 5 articles:

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