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Mendeleev Communications, 2021, Volume 31, Issue 2, Pages 176–178
DOI: https://doi.org/10.1016/j.mencom.2021.03.010
(Mi mendc870)
 

This article is cited in 10 scientific papers (total in 10 papers)

Communications

3-Amino-1,2,4-triazolium salts as NHC-proligands: synthesis and postmodification of a new type of amino-functionalized Pd/NHC complexes

D. V. Pasyukova, A. Yu. Chernenkoa, K. E. Shepelenkoa, V. V. Kutyreva, V. N. Khrustalevbc, V. M. Chernysheva

a Platov South-Russian State Polytechnic University, Novocherkassk, Russian Federation
b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
c Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation
Abstract: Palladium complexes with N-heterocyclic carbene ligands of a new type containing free NH2 group were obtained by direct palladation of 3-amino-1,4-dialkyl-1,2,4-triazolium salts. These amino-functionalized complexes were found to be a versatile platform for postmodification via reactions of the NH2 group with acyl and sulfonyl chlorides.
Keywords: 3-amino-1,2,4-triazole, N-heterocyclic carbenes, palladium complexes, postmodification, catalysis.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (3.2 Mb)


Citation: D. V. Pasyukov, A. Yu. Chernenko, K. E. Shepelenko, V. V. Kutyrev, V. N. Khrustalev, V. M. Chernyshev, “3-Amino-1,2,4-triazolium salts as NHC-proligands: synthesis and postmodification of a new type of amino-functionalized Pd/NHC complexes”, Mendeleev Commun., 31:2 (2021), 176–178
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  • This publication is cited in the following 10 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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