Abstract:
Palladium complexes with N-heterocyclic carbene ligands of a new type containing free NH2 group were obtained by direct palladation of 3-amino-1,4-dialkyl-1,2,4-triazolium salts. These amino-functionalized complexes were found to be a versatile platform for postmodification via reactions of the NH2 group with acyl and sulfonyl chlorides.
Citation:
D. V. Pasyukov, A. Yu. Chernenko, K. E. Shepelenko, V. V. Kutyrev, V. N. Khrustalev, V. M. Chernyshev, “3-Amino-1,2,4-triazolium salts as NHC-proligands: synthesis and postmodification of a new type of amino-functionalized Pd/NHC complexes”, Mendeleev Commun., 31:2 (2021), 176–178
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https://www.mathnet.ru/eng/mendc870
https://www.mathnet.ru/eng/mendc/v31/i2/p176
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