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Mendeleev Communications, 2021, Volume 31, Issue 2, Pages 244–245
DOI: https://doi.org/10.1016/j.mencom.2021.03.033 (Mi mendc893) 		 
This article is cited in 3 scientific papers (total in 3 papers)

Communications

The surprising diacylation of diethyl (ethoxycarbonylmethyl)phosphonate

K. V. Gulyás, G. T. Keglevich

Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
Full-text PDF (214 kB) Citations (3) Supplementary materials
DOI: https://doi.org/10.1016/j.mencom.2021.03.033
Abstract: Deprotonation of diethyl (ethoxycarbonylmethyl)-phosphonate with NaH followed by treatment with acyl chlorides affords surprisingly the corresponding C,C-diacylated derivatives as the predominating products.
Keywords: CH-acidic compounds, phosphonates, acylation, diacylation, relative DpKa value.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (394.5 Kb)


Citation: K. V. Gulyás, G. T. Keglevich, “The surprising diacylation of diethyl (ethoxycarbonylmethyl)phosphonate”, Mendeleev Commun., 31:2 (2021), 244–245
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  • https://www.mathnet.ru/eng/mendc/v31/i2/p244
    • This publication is cited in the following 3 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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