L. Wang, Ya. Wang, Yu. Tao, N. Zhang, Sh. Li, “Nickel catalyzed hydrosilane reduction of (het)arenecarboxylic acids into aldehydes”, Mendeleev Commun., 31:2 (2021), 271

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Mendeleev Communications, 2021, Volume 31, Issue 2, Pages 271–273
DOI: https://doi.org/10.1016/j.mencom.2021.03.043 (Mi mendc903)

This article is cited in 3 scientific papers (total in 3 papers)

Communications

Nickel catalyzed hydrosilane reduction of (het)arenecarboxylic acids into aldehydes

L. Wang^a, Ya. Wang^b, Yu. Tao^a, N. Zhang^a, Sh. Li^a

^a School of Chemical and Pharmaceutical Engineering, Changzhou Vocational Institute of Engineering, Changzhou, P.R. China
^b School of Petrochemical Engineering, Changzhou University, Changzhou, China

Full-text PDF (212 kB) Citations (3) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2021.03.043

Graphic abstract: Nickel catalyzed hydrosilane reduction of (het)arenecarboxylic acids into aldehydes

Abstract: Nickel-catalyzed reduction of (het)arenecarboxylic acids with hydrosilanes in the presence of dimethyl dicarbonate as the activator affords the corresponding aldehydes. The role of the activator is the conversion of the acids into their anhydrides undergoing C–O cleavage. The good yields were achieved in case of substrates bearing electron-donating and electron-neutral groups.

Keywords: nickel catalysis, C–O cleavage, arenecarboxylic acids, aldehydes, hydrosilanes, dimethyl dicarbonate.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(721.6 Kb)

Citation: L. Wang, Ya. Wang, Yu. Tao, N. Zhang, Sh. Li, “Nickel catalyzed hydrosilane reduction of (het)arenecarboxylic acids into aldehydes”, Mendeleev Commun., 31:2 (2021), 271–273

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https://www.mathnet.ru/eng/mendc/v31/i2/p271

This publication is cited in the following 3 articles:

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