Abstract:
Gradient copolymers of styrene and N-vinylpyrrolidone, obtained in bulk using the reversible deactivation radical polymerization process under the action of TEMPO nitroxide, can form microphase-like separated structures directly in the reaction medium without any additional treatment or solvent. The morphology of the resulting product is highly dependent on the monomer feed composition.
Citation:
M. Yu. Zaremski, E. Yu. Kozhunova, S. S. Abramchuk, M. E. Glavatskaya, A. V. Chertovich, “Polymerization-induced phase separation in gradient copolymers”, Mendeleev Commun., 31:2 (2021), 277–279
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https://www.mathnet.ru/eng/mendc905
https://www.mathnet.ru/eng/mendc/v31/i2/p277
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