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Mendeleev Communications, 2021, Volume 31, Issue 2, Pages 277–279
DOI: https://doi.org/10.1016/j.mencom.2021.03.045
(Mi mendc905)
 

This article is cited in 7 scientific papers (total in 7 papers)

Communications

Polymerization-induced phase separation in gradient copolymers

M. Yu. Zaremskia, E. Yu. Kozhunovab, S. S. Abramchukb, M. E. Glavatskayaa, A. V. Chertovichbc

a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b Department of Physics, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
c N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
Abstract: Gradient copolymers of styrene and N-vinylpyrrolidone, obtained in bulk using the reversible deactivation radical polymerization process under the action of TEMPO nitroxide, can form microphase-like separated structures directly in the reaction medium without any additional treatment or solvent. The morphology of the resulting product is highly dependent on the monomer feed composition.
Keywords: microphase separation, gradient copolymers, block copolymers, polymerization-induced self-assembly, nitroxide.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (307.8 Kb)


Citation: M. Yu. Zaremski, E. Yu. Kozhunova, S. S. Abramchuk, M. E. Glavatskaya, A. V. Chertovich, “Polymerization-induced phase separation in gradient copolymers”, Mendeleev Commun., 31:2 (2021), 277–279
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  • https://www.mathnet.ru/eng/mendc/v31/i2/p277
  • This publication is cited in the following 7 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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