O. E. Eremina, M. V. Samodelova, M. V. Ferree, T. N. Shekhovtsova, I. A. Veselova, “Capturing polycyclic aromatic sulfur heterocycles in electron donor–acceptor complexes”, Mendeleev Commun., 31:3 (2021), 326

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Mendeleev Communications, 2021, Volume 31, Issue 3, Pages 326–329
DOI: https://doi.org/10.1016/j.mencom.2021.04.015 (Mi mendc919)

This article is cited in 2 scientific papers (total in 2 papers)

Communications

Capturing polycyclic aromatic sulfur heterocycles in electron donor–acceptor complexes

O. E. Eremina, M. V. Samodelova, M. V. Ferree, T. N. Shekhovtsova, I. A. Veselova

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Full-text PDF (1310 kB) Citations (2) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2021.04.015

Graphic abstract: Capturing polycyclic aromatic sulfur heterocycles in electron donor–acceptor complexes

Abstract: Stoichiometry and stability of electron donor–acceptor complexes formed by dibenzothiophene and its alkylated derivatives with DDQ and TCNE in nonpolar organic solvents has been investigated. 4,6-Dimethyldibenzothiophene produces the most stable 1: 1 complex with DDQ in agreement with energy levels of the π-donors HOMOs and π-acceptors LUMOs calculated by DFT. The results make possible an employment of the complexes for multiplex determination of polycyclic aromatic pollutants using surface enhanced Raman spectroscopy.

Keywords: polycyclic aromatic sulfur heterocycles, dibenzothiophene, charge transfer complex, optical sensor, surface enhanced Raman spectroscopy, multiplex detection, silver nanoparticles.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.0 Mb)

Citation: O. E. Eremina, M. V. Samodelova, M. V. Ferree, T. N. Shekhovtsova, I. A. Veselova, “Capturing polycyclic aromatic sulfur heterocycles in electron donor–acceptor complexes”, Mendeleev Commun., 31:3 (2021), 326–329

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https://www.mathnet.ru/eng/mendc919

https://www.mathnet.ru/eng/mendc/v31/i3/p326

This publication is cited in the following 2 articles:

Citing articles in Google Scholar: Russian citations, English citations
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