O. A. Levitskiy, O. I. Aglamazova, A. V. Dmitrieva, V. A. Soloshonok, H. Moriwaki, Yu. K. Grishin, T. V. Magdesieva, “Stereoselective arylthiolation of dehydroalanine in the NiII coordination environment: the stereoinductor of choice”, Mendeleev Commun., 31:3 (2021), 337

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Mendeleev Communications, 2021, Volume 31, Issue 3, Pages 337–340
DOI: https://doi.org/10.1016/j.mencom.2021.04.018 (Mi mendc922)

This article is cited in 9 scientific papers (total in 9 papers)

Communications

Stereoselective arylthiolation of dehydroalanine in the Ni^II coordination environment: the stereoinductor of choice

O. A. Levitskiy^a, O. I. Aglamazova^a, A. V. Dmitrieva^a, V. A. Soloshonok^bc, H. Moriwaki^d, Yu. K. Grishin^a, T. V. Magdesieva^a

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b IKERBASQUE, Basque Foundation for Science, Bilbao, Spain
^c Department of Organic Chemistry I, Faculty of Chemistry, University of Basque Country UPV/EHU, San Sebastian, Spain
^d Hamari Chemical Ltd, Osaka, Japan

Full-text PDF (278 kB) Citations (9) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2021.04.018

Graphic abstract: Stereoselective arylthiolation of dehydroalanine in the Ni<sup>II</sup> coordination environment: the stereoinductor of choice

Abstract: Arylthiolation of new dehydroalanine Ni^II Schiff-base complex containing (S)-2-[N-(N′-2,3-dichlorobenzylprolyl)amino]-5-chlorobenzophenone auxiliary affords (S,R)-cysteine derivatives in high chemical yield (65–88%) and with excellent diastereoselectivity (de up to 91%), which significantly exceeds that for the commonly used analogue depriving of three chlorine atoms.

Keywords: stereoselective synthesis, chiral template, Schiff bases, nickel complexes, arylthiolation, sulfides, cysteine derivatives, Michael addition.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(9.5 Mb)

Citation: O. A. Levitskiy, O. I. Aglamazova, A. V. Dmitrieva, V. A. Soloshonok, H. Moriwaki, Yu. K. Grishin, T. V. Magdesieva, “Stereoselective arylthiolation of dehydroalanine in the Ni^II coordination environment: the stereoinductor of choice”, Mendeleev Commun., 31:3 (2021), 337–340

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https://www.mathnet.ru/eng/mendc922

https://www.mathnet.ru/eng/mendc/v31/i3/p337

This publication is cited in the following 9 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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