N. V. Shvydkiy, D. S. Perekalin, “Cyclobutadiene cobalt complexes as catalysts for insertion of diazo compounds into X–H bonds”, Mendeleev Commun., 31:3 (2021), 350

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Mendeleev Communications, 2021, Volume 31, Issue 3, Pages 350–351
DOI: https://doi.org/10.1016/j.mencom.2021.04.022 (Mi mendc926)

This article is cited in 5 scientific papers (total in 5 papers)

Communications

Cyclobutadiene cobalt complexes as catalysts for insertion of diazo compounds into X–H bonds

N. V. Shvydkiy^a, D. S. Perekalin^ab

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation

Full-text PDF (216 kB) Citations (5) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2021.04.022

Graphic abstract: Cyclobutadiene cobalt complexes as catalysts for insertion of diazo compounds into X–H bonds

Abstract: Novel cyclobutadiene cobalt complex with labile naphthalene ligand [(C₄Et₄)Co(C₁₀H₈)]PF₆ catalyzes the insertion of ethyl diazoacetate into X–H bonds giving the corresponding products in 15–75% yields. The reaction proceeds with primary and secondary aliphatic amines, hydrosilanes and triethylamine borane but not with anilines and alcohols.

Keywords: cyclobutadiene, cobalt complexes, catalysis, diazo compounds, insertion, organosilicon compounds.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.2 Mb)

Citation: N. V. Shvydkiy, D. S. Perekalin, “Cyclobutadiene cobalt complexes as catalysts for insertion of diazo compounds into X–H bonds”, Mendeleev Commun., 31:3 (2021), 350–351

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https://www.mathnet.ru/eng/mendc926

https://www.mathnet.ru/eng/mendc/v31/i3/p350

This publication is cited in the following 5 articles:

Citing articles in Google Scholar: Russian citations, English citations
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