A. V. Churakov, A. V. Medved'ko, P. V. Prikhodchenko, D. P. Krut'ko, S. Z. Vatsadze, “First example of peroxosolvate of iodine-containing organic molecule”, Mendeleev Commun., 31:3 (2021), 352

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Mendeleev Communications, 2021, Volume 31, Issue 3, Pages 352–355
DOI: https://doi.org/10.1016/j.mencom.2021.04.023 (Mi mendc927)

This article is cited in 9 scientific papers (total in 9 papers)

Communications

First example of peroxosolvate of iodine-containing organic molecule

A. V. Churakov^a, A. V. Medved'ko^b, P. V. Prikhodchenko^a, D. P. Krut'ko^c, S. Z. Vatsadze^b

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Full-text PDF (793 kB) Citations (9) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2021.04.023

Graphic abstract: First example of peroxosolvate of iodine-containing organic molecule

Abstract: Six new bispidine-based bis-amides containing residues of haloacetic acids were synthesized and characterized by X-ray crystallography. The dissolution of iodine-containing compound in concentrated hydrogen peroxide afforded bispidine peroxosolvate, in which the peroxide molecules participated in two donor hydrogen bonds with carbonyl oxygen atoms of the distinct adjacent organic molecules thus forming cyclic motifs in crystals. This structure is a first example of peroxosolvate of iodine-containing organic molecule.

Keywords: 3,7-diazabicyclo[3.3.1]nonane, α-halo carbonyl compounds, hydrogen peroxide, peroxosolvates, organoiodine compounds, conformation analysis, X-ray diffraction study.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(3.0 Mb)

Citation: A. V. Churakov, A. V. Medved'ko, P. V. Prikhodchenko, D. P. Krut'ko, S. Z. Vatsadze, “First example of peroxosolvate of iodine-containing organic molecule”, Mendeleev Commun., 31:3 (2021), 352–355

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https://www.mathnet.ru/eng/mendc927

https://www.mathnet.ru/eng/mendc/v31/i3/p352

This publication is cited in the following 9 articles:

Citing articles in Google Scholar: Russian citations, English citations
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