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Nanosystems: Physics, Chemistry, Mathematics, 2011, Volume 2, Issue 3, Pages 93–101 (Mi nano639)  

CHEMISTRY

On the limiting thickness of the Perovskite-like block in the Aurivillius phases in the Bi$_2$O$_3$–Fe$_2$O$_3$–TiO$_2$ system

N. A. Lomanovaa, V. V. Gusarovab

a Ioffe Institute, St. Petersburg
b State Technological Institute of St. Petersburg (Technical University)
Abstract: The stability of the Aurivillius phases in the system Bi$_2$O$_3$–Fe$_2$O$_3$–TiO$_2$ was investigated. Structural and physicochemical parameters, allowing to calculate the limits of the length of the homologous series of the compounds Bi$_{n+1}$Fe$_{n-3}$Ti$_3$O$_{3n+3}$ were identified. It was found that the maximum thickness of a perovskite-like block of these compounds is $\sim$3.7 nm.
Keywords: oxides; layered compounds; the Aurivillius phases.
Bibliographic databases:
Document Type: Article
UDC: 541.124
PACS: 61.66.Fn
Language: Russian
Citation: N. A. Lomanova, V. V. Gusarov, “On the limiting thickness of the Perovskite-like block in the Aurivillius phases in the Bi$_2$O$_3$–Fe$_2$O$_3$–TiO$_2$ system”, Nanosystems: Physics, Chemistry, Mathematics, 2:3 (2011), 93–101
Citation in format AMSBIB
\Bibitem{LomGus11}
\by N.~A.~Lomanova, V.~V.~Gusarov
\paper On the limiting thickness of the Perovskite-like block in the Aurivillius phases in the Bi$_2$O$_3$--Fe$_2$O$_3$--TiO$_2$ system
\jour Nanosystems: Physics, Chemistry, Mathematics
\yr 2011
\vol 2
\issue 3
\pages 93--101
\mathnet{http://mi.mathnet.ru/nano639}
\elib{https://elibrary.ru/item.asp?id=17068206}
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