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Optics and Spectroscopy, 2022, Volume 130, Issue 1, Pages 92–98
DOI: https://doi.org/10.21883/OS.2022.01.51894.20-21
(Mi os1644)
 

Materials of the International Seminar of the Institute of Spectroscopy of the Russian Academy of Sciences (ISAN), dedicated to the anniversary of Professor M.N. Popova
Spectroscopy of condensed state

Spectral-luminescence properties of ZrO$_2$–Sc$_2$O$_3$–Tb$_2$O$_3$ crystals

S. Kh. Batygova, M. A. Borika, A. V. Kulebyakina, N. A. Larinab, E. E. Lomonovaa, V. A. Myzinaa, P. A. Ryabochkinab, N. V. Sidorovab, A. D. Taratynovab, N. Yu. Tabachkovaac

a Prokhorov General Physics Institute of the Russian Academy of Sciences, Moscow, Russia
b Ogarev Mordovia State University, 430005 Saransk, Russia
c National University of Science and Technology «MISIS», Moscow, Russia
Abstract: Crystals of the concentration series ZrO$_2$–(8–10) mol.% Sc$_2$O$_3$–(1–2) mol.% Tb$_2$O$_3$ were grown by the method of directional crystallization of the melt from a cold container. Analysis of the spectral-luminescence characteristics of these crystals after growth and after annealing processing in a vacuum revealed the presence of both Tb$^{3+}$ and Tb$^{4+}$ ions in them. In crystals ZrO$_2$–(8–10) mol.% Sc$_2$O$_3$–(1–2) mol.% Tb$_2$O$_3$, the presence of a process of non-radiative energy transfer from Tb$^{4+}$ ions to Tb$^{3+}$ ions was revealed.
Keywords: solid solutions of zirconium dioxide, luminescence, terbium ions.
Funding agency Grant number
Russian Science Foundation 19-72-10113
Ministry of Science and Higher Education of the Russian Federation 075-15-2021-696
This study was financially supported by the grant of Russian Science Foundation № 19-72-10113. Structure study was performed using equipment of “Materials Science and Metallurgy” Common Use Center with financial support of the Russian Federation presented by the Ministry of Education and Science (№ 075-15-2021-696).
Received: 28.06.2021
Revised: 28.06.2021
Accepted: 08.09.2021
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: S. Kh. Batygov, M. A. Borik, A. V. Kulebyakin, N. A. Larina, E. E. Lomonova, V. A. Myzina, P. A. Ryabochkina, N. V. Sidorova, A. D. Taratynova, N. Yu. Tabachkova, “Spectral-luminescence properties of ZrO$_2$–Sc$_2$O$_3$–Tb$_2$O$_3$ crystals”, Optics and Spectroscopy, 130:1 (2022), 92–98
Citation in format AMSBIB
\Bibitem{BatBorKul22}
\by S.~Kh.~Batygov, M.~A.~Borik, A.~V.~Kulebyakin, N.~A.~Larina, E.~E.~Lomonova, V.~A.~Myzina, P.~A.~Ryabochkina, N.~V.~Sidorova, A.~D.~Taratynova, N.~Yu.~Tabachkova
\paper Spectral-luminescence properties of ZrO$_2$--Sc$_2$O$_3$--Tb$_2$O$_3$ crystals
\jour Optics and Spectroscopy
\yr 2022
\vol 130
\issue 1
\pages 92--98
\mathnet{http://mi.mathnet.ru/os1644}
\crossref{https://doi.org/10.21883/OS.2022.01.51894.20-21}
\elib{https://elibrary.ru/item.asp?id=48001473}
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