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This article is cited in 1 scientific paper (total in 1 paper)
Materials of the International Seminar of the Institute of Spectroscopy of the Russian Academy of Sciences (ISAN), dedicated to the anniversary of Professor M.N. Popova
Spectroscopy of condensed state
Electron-phonon interaction in composites with colloidal quantum dots: a study by luminescence spectroscopy and Raman scattering
K. R. Karimullinabc, A. I. Arzhanovab, N. V. Surovtsevd, A. V. Naumovabc a Institute of Spectroscopy, Russian Academy of Sciences, 108840 Troitsk, Moscow, Russia
b Moscow State Pedagogical University, 119435 Moscow, Russia
c Lebedev Physical Institute, Russian Academy of Sciences, Troitsk Separate Subdivision, including "Troitsky Technopark LPI
RAS", 108840 Troitsk, Moscow, Russia
d Institute of Automation and Electrometry, Siberian Branch of Russian Academy of Sciences, 630090 Novosibirsk, Russia
Abstract:
The temperature-dependent luminescence spectra were analyzed to determine the parameters of the electron-phonon interaction (Huang-Rhys factor and the average phonon energy) for nanocomposites with colloidal CdSe/CdS/ZnS quantum dots (deposited on the surface of a glass substrate and embedded in a thin polymer film of polyisobutylene, and in a frozen colloidal solution in toluene). The measured values of the parameters are analyzed in comparison with model calculations and data obtained using the low-frequency Raman spectroscopy. It is found that in the case of a vitrified colloidal solution of quantum dots in toluene, the matrix effect leads to a noticeable change in the parameters of the electron-phonon interaction.
Keywords:
quantum dot, nanocomposite, polymer, phonon, electron-phonon interaction.
Received: 20.08.2021 Revised: 06.09.2021 Accepted: 14.09.2021
Citation:
K. R. Karimullin, A. I. Arzhanov, N. V. Surovtsev, A. V. Naumov, “Electron-phonon interaction in composites with colloidal quantum dots: a study by luminescence spectroscopy and Raman scattering”, Optics and Spectroscopy, 130:1 (2022), 146–150
Linking options:
https://www.mathnet.ru/eng/os1652 https://www.mathnet.ru/eng/os/v130/i1/p146
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