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Fizika i Tekhnika Poluprovodnikov, 2021, Volume 55, Issue 5, Pages 450–454
DOI: https://doi.org/10.21883/FTP.2021.05.50836.9578
(Mi phts5040)
 

Amorphous, glassy, organic semiconductors

Charge transfer in thin layers of glassy Ge$_{28.5}$Pb$_{14.5}$Fe$_{0.5}$S$_{56.5}$

R. A. Kastro-Arataa, G. I. Grabkoab, A. A. Kononova, N. I. Anisimovaa, M. Krbalc, A. V. Kolobovad

a Herzen State Pedagogical University of Russia, St. Petersburg
b Zabaikalsky State University, Chita
c Университет Пардубице, 530 02 Пардубице, Чехия
d National Institute of Advanced Industrial Science and Technology, Tsukuba, Japan
Abstract: The results of investigation of charge transfer processes in thin layers of vitreous Ge$_{28.5}$Pb$_{14.5}$Fe$_{0.5}$S$_{56.5}$ are presented. The power-law dependence of specific conductivity on frequency and a decrease of the power exponent s value with increasing temperature were found. The charge transfer is a thermally ac- tivated process with the activation energy $E_a$ = (0.64 $\pm$ 0.02) eV. The results obtained are explained within the correlated barrier hopping model (CBH) of conductivity in disordered systems. The calculated concentration of lone-pair electrons L demonstrates that the material remains in the glass-forming region.
Keywords: hopping transfer mechanism, thin layers, glassy hybrid system, lone-pair electrons.
Funding agency Grant number
Russian Foundation for Basic Research 19-53-26017 (Чехия_а)
Czech Science Foundation (GACR) 20-23392J
Received: 18.01.2021
Revised: 25.01.2021
Accepted: 25.01.2021
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: R. A. Kastro-Arata, G. I. Grabko, A. A. Kononov, N. I. Anisimova, M. Krbal, A. V. Kolobov, “Charge transfer in thin layers of glassy Ge$_{28.5}$Pb$_{14.5}$Fe$_{0.5}$S$_{56.5}$”, Fizika i Tekhnika Poluprovodnikov, 55:5 (2021), 450–454
Citation in format AMSBIB
\Bibitem{KasGraKon21}
\by R.~A.~Kastro-Arata, G.~I.~Grabko, A.~A.~Kononov, N.~I.~Anisimova, M.~Krbal, A.~V.~Kolobov
\paper Charge transfer in thin layers of glassy Ge$_{28.5}$Pb$_{14.5}$Fe$_{0.5}$S$_{56.5}$
\jour Fizika i Tekhnika Poluprovodnikov
\yr 2021
\vol 55
\issue 5
\pages 450--454
\mathnet{http://mi.mathnet.ru/phts5040}
\crossref{https://doi.org/10.21883/FTP.2021.05.50836.9578}
\elib{https://elibrary.ru/item.asp?id=46474556}
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