Kinetics of the Thermal Decomposition of N-Nitro-compounds

Results primarily on nitramines are summarised. Analysis of modern views indicates that a non-chain radical mechanism with rupture of the N–NO₂ bond in the rate-determining stage is the most soundly based. Kinetic parameters of the thermal decomposition of N-nitro-compounds are systematised. The kinetic role of phase constitution is discussed, and prospects for future research are considered. A list of 108 references is included.