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Zhurnal Tekhnicheskoi Fiziki, 2023, Volume 93, Issue 2, Pages 249–255
DOI: https://doi.org/10.21883/JTF.2023.02.54500.221-22n
(Mi jtf6940)
 

Physical science of materials

Influence of synthesis conditions on the structural, optical, and electrophysical properties of TiO$_2$/Cu$_x$O nanocomposites

M. N. Martyshova, A. V. Pavlikovba, E. V. Kytinaa, O. V. Pinchukb, T. P. Savchukab, E. A. Konstantinovaa, V. B. Zaitseva, P. K. Kashkarovac

a Department of Physics, Moscow State University, 119991 Moscow, Russia
b National Research University of Electronic Technology, 124498 Zelenograd, Moscow, Russia
c National Research Centre "Kurchatov Institute", 123182 Moscow, Russia
Abstract: Nanocomposites based on anodic titanium oxide nanotubes with copper oxide nanoparticles were formed and their structural, optical, and electrophysical properties were studied. Defects in the structure of the samples were identified by electron paramagnetic resonance and it was shown that, as a result of copper oxide deposition, CuO nanoparticles were formed on the surface of nanotubes. It was found that the conductivity of the structure decreases by several orders of magnitude with an increase in the number of deposition cycles. It was shown that this effect could be associated with the formation of TiO$_2$/CuO heterojunctions on the nanotube surface. It was shown for the first time that an increase in the content of copper oxide in TiO$_2$/Cu$_x$O nanocomposites was accompanied by a decrease in conductivity and an increase in the number of defects.
Keywords: titanium oxide, nanotubes, nanocomposites, copper oxide nanoparticles, defects, conductivity.
Funding agency Grant number
Russian Science Foundation 21-19-00494
This study was supported by grant No. 21-19-00494 from the Russian Science Foundation (https://rscf.ru/en/project/21-19-00494/).
Received: 08.09.2022
Revised: 01.12.2022
Accepted: 06.12.2022
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: M. N. Martyshov, A. V. Pavlikov, E. V. Kytina, O. V. Pinchuk, T. P. Savchuk, E. A. Konstantinova, V. B. Zaitsev, P. K. Kashkarov, “Influence of synthesis conditions on the structural, optical, and electrophysical properties of TiO$_2$/Cu$_x$O nanocomposites”, Zhurnal Tekhnicheskoi Fiziki, 93:2 (2023), 249–255
Citation in format AMSBIB
\Bibitem{MarPavKyt23}
\by M.~N.~Martyshov, A.~V.~Pavlikov, E.~V.~Kytina, O.~V.~Pinchuk, T.~P.~Savchuk, E.~A.~Konstantinova, V.~B.~Zaitsev, P.~K.~Kashkarov
\paper Influence of synthesis conditions on the structural, optical, and electrophysical properties of TiO$_2$/Cu$_x$O nanocomposites
\jour Zhurnal Tekhnicheskoi Fiziki
\yr 2023
\vol 93
\issue 2
\pages 249--255
\mathnet{http://mi.mathnet.ru/jtf6940}
\crossref{https://doi.org/10.21883/JTF.2023.02.54500.221-22n}
\elib{https://elibrary.ru/item.asp?id=50361184}
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