A. R. Petrov, K. A. Rufanov, N. K. Hangaly, M. Elfferding, K. Harms, J. Sundermeyer, “Air-stable helical bis(cyclopentadienylphosphazene) complexes of divalent ytterbium”, Mendeleev Commun., 20:4 (2010), 197

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Mendeleev Communications, 2010, Volume 20, Issue 4, Pages 197–199
DOI: https://doi.org/10.1016/j.mencom.2010.06.004 (Mi mendc3036)

This article is cited in 10 scientific papers (total in 10 papers)

Air-stable helical bis(cyclopentadienylphosphazene) complexes of divalent ytterbium

A. R. Petrov^a, K. A. Rufanov^b, N. K. Hangaly^a, M. Elfferding^a, K. Harms^a, J. Sundermeyer^a

^a Fachbereich Chemie der Universität Marburg, Marburg, Germany
^b Department of Organic Chemistry, Chemical Diversity Research Institute, Khimki, Moscow Region, Russian Federation

Full-text PDF (498 kB) Citations (10)

DOI: https://doi.org/10.1016/j.mencom.2010.06.004

Abstract: Two homoleptic Yb^II constrained geometry complexes [Yb{η⁵,η¹-R₂P(C₅Me₄)NAd}₂] [R =Me (3), Ph (4); Ad=1-adamantyl] derived from P-amino(cyclopentadienylidene)phosphoranes (CpPN) R₂P(C₅Me₄)NHAd [R=Me (1), Ph (2)] were found to be remarkably stable towards dioxygen, as shown by NMR spectroscopy and further confirmed by the crystal structure analysis of 4 and discussed in terms of efficient steric shielding and electronic stabilization of the Yb^II metal centre by this CpPN ligand type.

Keywords: divalent ytterbium, oxidative stable, cyclopentadienyl-phosphazene ligand, constrained geometry complexes, Staudinger reaction.

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(38.1 Kb)

Citation: A. R. Petrov, K. A. Rufanov, N. K. Hangaly, M. Elfferding, K. Harms, J. Sundermeyer, “Air-stable helical bis(cyclopentadienylphosphazene) complexes of divalent ytterbium”, Mendeleev Commun., 20:4 (2010), 197–199

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https://www.mathnet.ru/eng/mendc/v20/i4/p197

This publication is cited in the following 10 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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