A. G. Kutasevich, Ya. S. Novoselskaya, E. A. Kvyatkovskaya, N. A. Nikolaev, V. V. Brazhkin, F. I. Zubkov, E. V. Nikitina, “Tandem [4 + 2]/[4 + 2] cycloaddition of bis-furyl dienes with fumaric and maleic esters at ultra-high pressure”, Mendeleev Commun., 35:3 (2025), 252

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Mendeleev Communications, 2025, Volume 35, Issue 3, Pages 252–254
DOI: https://doi.org/10.71267/mencom.7673 (Mi mendc6151)

Communications

Tandem [4 + 2]/[4 + 2] cycloaddition of bis-furyl dienes with fumaric and maleic esters at ultra-high pressure

A. G. Kutasevich^a, Ya. S. Novoselskaya^a, E. A. Kvyatkovskaya^a, N. A. Nikolaev^b, V. V. Brazhkin^b, F. I. Zubkov^a, E. V. Nikitina^a

^a Peoples Friendship University of Russia (RUDN University), 117198 Moscow, Russian Federation
^b Institute for High Pressure Physics, Russian Academy of Sciences, 108840 Troitsk, Moscow, Russian Federation

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DOI: https://doi.org/10.71267/mencom.7673

Graphic abstract: Tandem [4 + 2]/[4 + 2] cycloaddition of bis-furyl dienes with fumaric and maleic esters at ultra-high pressure

Abstract: Employment of ultra-high pressures (15 kbar) at room temperature makes it possible to prepare 1,4:5,8-diepoxynaphthalenes annulated with other heterocycles from bisfurfuryl derivatives and fumaric/maleic esters. Such a reaction does not proceed under ordinary thermal conditions.

Keywords: intramolecular Diels–Alder reaction, furan, 7-oxabicyclo[2.2.1]heptene, ultra-high pressure, fumaric esters, maleic esters, 1,4:5,8-diepoxynaphthalene.

Funding agency	Grant number
Russian Science Foundation	23–23-00577

Received: 01.11.2024
Accepted: 05.12.2024

Published: 31.03.2025

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(8.2 Mb)

Citation: A. G. Kutasevich, Ya. S. Novoselskaya, E. A. Kvyatkovskaya, N. A. Nikolaev, V. V. Brazhkin, F. I. Zubkov, E. V. Nikitina, “Tandem [4 + 2]/[4 + 2] cycloaddition of bis-furyl dienes with fumaric and maleic esters at ultra-high pressure”, Mendeleev Commun., 35:3 (2025), 252–254

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