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This article is cited in 1 scientific paper (total in 1 paper)
CHEMISTRY AND MATERIAL SCIENCE
Study of photocatalytic activity in two light ranges of Sr$_2$Mn$_{0.4}$Ti$_{0.6}$O$_4$ oxide with the K$_2$NiF$_4$-type structure
Tatyana I. Chupakhinaa, Olga I. Gyrdasovaa, Anastasya M. Uporovaa, Larisa Yu. Buldakovaa, Mikhail Yu. Yanchenkoa, Dzhavid V. Mamedovb, Yulia A. Deevaa, Inna V. Baklanovaa a Institute of Solid State Chemistry UB RAS, Ekaterinburg, Russia
b Zavoisky Physical-Technical Institute, FRC Kazan Scientific Center of RAS, Kazan, Russia
Abstract:
The photocatalytic properties of single-phase sample Sr$_2$Mn$_{0.4}$Ti$_{0.6}$O$_4$ is studied as a representative of a series of Sr$_2$Mn$_x$Ti$_{1-x}$O$_4$ solid solutions ($x$ = 0.05, 0.15, 0.25, 0.4) obtained by the SHS. The sample annealed at 1200$^\circ$C is characterized by a uniform distribution of Sr, Ti and Mn in the oxidation degree (4+) inside the aggregates, the average size of which does not exceed 1$\mu$m. According to UV-Vis-NIR spectroscopy data, a narrowing of the band gap of Sr$_2$TiO$_4$ from 3.16 to 1.8 eV is observed when it is doped with 40 mol% of manganese. This is due to the high photoactivity of Sr$_2$Mn$_{0.4}$Ti$_{0.6}$O$_4$ in the HQ oxidation reaction in UV and blue light.
Keywords:
nanostructured strontium titanate, Raddlesden–Popper structures, oxidative photocatalysis.
Received: 17.06.2024 Revised: 13.08.2024 Accepted: 14.08.2024
Citation:
Tatyana I. Chupakhina, Olga I. Gyrdasova, Anastasya M. Uporova, Larisa Yu. Buldakova, Mikhail Yu. Yanchenko, Dzhavid V. Mamedov, Yulia A. Deeva, Inna V. Baklanova, “Study of photocatalytic activity in two light ranges of Sr$_2$Mn$_{0.4}$Ti$_{0.6}$O$_4$ oxide with the K$_2$NiF$_4$-type structure”, Nanosystems: Physics, Chemistry, Mathematics, 15:4 (2024), 540–547
Linking options:
https://www.mathnet.ru/eng/nano1298 https://www.mathnet.ru/eng/nano/v15/i4/p540
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