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This article is cited in 3 scientific papers (total in 3 papers)
Thermophysical Properties of Materials
Thermodynamics of the evaporation of yttrium triiodide in the form of $\rm YI_3$ and $\rm Y_2\rm I_6$ molecules
E. L. Osinaa, L. N. Gorokhova, S. B. Osinb a Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow
b Lomonosov Moscow State University, Faculty of Chemistry
Abstract:
In this paper, we select the values of the molecular constants and calculate the thermodynamic functions of $\rm YI_3$ and $\rm Y_2\rm I_6$ based on a critical analysis of experimental and theoretical data on the structure and vibration frequencies of the monomeric and dimeric forms of yttrium triiodide molecules. Using the literature data on the ratio of the partial pressures of dimeric and monomeric molecules and the third law of thermodynamics, we determine the enthalpy of the $\rm YI_3(\text{cr., l}) + \rm YI_3(\text{g}) = \rm Y_2\rm I_6(\text{g})$ reaction and calculate the composition of the yttrium iodide vapor in the temperature range of $800$–$961$ K, for which there are literature data on the total pressure. In the considered temperature range, the $P_{\text{d}}/P_{\text{m}}$ pressure ratio is found to increase from $0.003$ to $0.014$. The determined partial pressures are used to calculate the sublimation enthalpies of yttrium triiodide in the form of monomeric and dimeric molecules and the formation enthalpies of these molecules. The obtained values have been entered into the database of the IVTANTHERMO software package.
Received: 18.03.2020 Revised: 18.03.2020 Accepted: 18.06.2020
Citation:
E. L. Osina, L. N. Gorokhov, S. B. Osin, “Thermodynamics of the evaporation of yttrium triiodide in the form of $\rm YI_3$ and $\rm Y_2\rm I_6$ molecules”, TVT, 58:5 (2020), 764–769; High Temperature, 58:5 (2020), 694–698
Linking options:
https://www.mathnet.ru/eng/tvt11372 https://www.mathnet.ru/eng/tvt/v58/i5/p764
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