Аннотация:
Treatment of a bulky dbhmp-bian ligand (dbhmp-bian==1,2-bis[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene) by 1 equiv. of LiAlH4 or mixture of 3/4 equiv. LiAlH4 and 1/3 eqiuv. AlCl3 in tetrahydrofuran results in new hydrides [(dbhmp-bian)AlH2(THF)]-[Li(THF)4]+ and (dbhmp-bian)AlH(THF), respectively. Both complexes were characterized by spectroscopic (IR, NMR) and X-ray diffraction methods.
Образец цитирования:
M. V. Moskalev, D. A. Razborov, A. A. Bazanov, V. G. Sokolov, T. S. Koptseva, E. V. Baranov, I. L. Fedushkin, “One-step synthesis of new aluminum hydrides bearing a highly sterically hindered acenaphthene-1,2-diimine ligand”, Mendeleev Commun., 30:1 (2020), 94–96
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