Аннотация:
Synthesis and response towards heating and UV irradiation of two novel zinc(II) cyclobutane-1,1′-dicarboxylate complexes were examined using X-ray diffraction, FT-IR and 1H NMR spectroscopy. One of the complexes underwent a photoinitiated solid state transformation of 1,2-bis(pyrid-4-yl)ethylene into 1,2,3,4-tetrakis(pyrid-4-yl)cyclobutane. A preliminary dehydration of this solid decreases the conversion rate of photoreaction.
Образец цитирования:
I. E. Ushakov, A. S. Goloveshkin, E. N. Zorina-Tikhonova, A. S. Chistyakov, A. A. Sidorov, I. L. Eremenko, A. D. Volodin, A. V. Vologzhanina, “Synthesis, crystal structures and solid state reactions of zinc(ii) cyclobutane-1,1′-dicarboxylates containing 1,2-bis(pyrid-4 yl)ethylene”, Mendeleev Commun., 29:6 (2019), 643–645