Аннотация:
Aminomethylation of thiophosphorylated calix[4]resorcinol with formaldehyde and secondary amines affords the novel Mannich base derivatives possessing better solubility. The nickel complex of morpholinomethyl derivative exhibits a good catalytic activity in hydrogen evolution decreasing potential of direct acid reduction on glassy carbon electrode to 1.3V.
Образец цитирования:
I. R. Mironova (Knyazeva), V. I. Matveeva, V. V. Khrizanforova, Yu. H. Budnikova, A. R. Burilov, “Novel thiophosphorylated calix[4]resorcinol Mannich bases and their electrochemical behavior in hydrogen evolution reaction”, Mendeleev Commun., 28:5 (2018), 515–517