Аннотация:
The paramagnetic PdI centers with unpaired electrons have been first revealed by EPR spectroscopy in the polymeric matrices of PdI sorbates [Pd(C6H7O2)H2O]n, [Pd(C6H7O2)]n and 4-pentenate [Pd(C5H7O2)H2O]n. These compounds have been obtained by the reactions between Pd3(MeCO2)6 and sorbic (MeCH=CHCH=CHCOOH) and 4-pentenoic (CH2=CHCH2CH2COOH) acids in MeOH.
Реферативные базы данных:
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
I. A. Efimenko, O. S. Erofeeva, E. A. Ugolkova, N. N. Efimov, L. I. Demina, P. V. Grishanova, V. V. Minin, “Paramagnetic Pd+ centers in the polymeric matrices of palladium(I) sorbates and 4-pentenate”, Mendeleev Commun., 28:6 (2018), 632–634