Аннотация:
The enthalpies of dissolution of metastable rock salt (rs-ZnO) and thermodynamically stable wurtzite (w-ZnO) polymorphs of zinc oxide in aqueous H2SO4 have been measured in direct calorimetric experiments at 303K and 0.1MPa. Based on the obtained results, the standard enthalpy of the rs-ZnO to w-ZnO phase transition, ΔtrH = 11.7 ± 0.3kJ mol–1, has been determined.
Реферативные базы данных:
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
F. Yu. Sharikov, P. S. Sokolov, A. N. Baranov, V. L. Solozhenko, “On the thermodynamic aspect of zinc oxide polymorphism: calorimetric study of metastable rock salt ZnO”, Mendeleev Commun., 27:6 (2017), 613–614