Аннотация:
The formation of a PdCu alloy with an fcc structure in 1% Pd–1.2% Cu2 /Al2O3 (as evidenced by XRD and EXAFS data) significantly improves catalyst selectivity in the semihydrogenation of internal and terminal alkynes, which makes 1% Pd–1.2% Cu2 /Al2O3 a promising alternative to the commercial Lindlar catalyst.
Образец цитирования:
P. V. Markov, G. O. Bragina, A. V. Rassolov, G. N. Baeva, I. S. Mashkovsky, V. Yu. Murzin, Ya. V. Zubavichus, A. Yu. Stakheev, “Pd–Cu catalyst prepared from heterobimetallic PdCu2(OAc)6: an XRD-EXAFS study and activity/selectivity in the liquid-phase hydrogenation of a C≡C bond”, Mendeleev Commun., 26:6 (2016), 502–504