Аннотация:
The (cyclohexadienyl)iron complex Cp*Fe(η5-C6H7) obtained by a reaction of the cation [Cp*Fe(η6-C6H6)]+ with LiAlH4 reacts with HBF4·Et2O or TfOH in MeCN to afford the acetonitrile cation [Cp*Fe(MeCN)3]+ in a high yield. The structure of complex Cp*Fe(η5-C6H7) was determined by X-ray diffraction analysis.
Реферативные базы данных:
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
A. S. Romanov, M. M. Vinogradov, D. V. Muratov, A. R. Kudinov, “Protonation of Cp*Fe(η5-C6H7) as a convenient procedure for the preparation of the valuable synthon [Cp*Fe(MeCN)3]+”, Mendeleev Commun., 24:6 (2014), 358–359
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