|
Эта публикация цитируется в 9 научных статьях (всего в 9 статьях)
Volume of electrostriction of the solvate-separated ions of lithium perchlorate and contact ion pair of the transition state in sulfenyl insertion
V. D. Kiselev
Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation
Аннотация:
The volumes of electrostriction of the ions of lithium perchlorate are in a linear relation with the solvent electrostriction parameter ∂(1/ϵ)/∂p but the volume changes of ion pair transition state of electrophilic addition of aryl sulfenyl chloride to styrene and cyclohexene have the slope about 20 times less.
Ключевые слова:
sulfenyl chloride; volume of activation; solvent effect; electrostriction; mechanism.
Образец цитирования:
V. D. Kiselev, “Volume of electrostriction of the solvate-separated ions of lithium perchlorate and contact ion pair of the transition state in sulfenyl insertion”, Mendeleev Commun., 18:1 (2008), 59–61
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc3246 https://www.mathnet.ru/rus/mendc/v18/i1/p59
|
|
Обратная связь: