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Эта публикация цитируется в 1 научной статье (всего в 1 статье)
Resolution and racemization of nonbenzenoid atropenantiomers
P. V. Novikova, O. R. Malyshevb, K. A. Lyssenkoc, R. G. Kostyanovskya
a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Аннотация:
The three-step synthesis of adduct 3 has been reinvestigated; enantiomers 3a and 3b have been separated by enantioselective chromatography and the racemization barrier of 3a was determined as ΔG≠ = 24.4 kcal mol−1 (16 °C).
Образец цитирования:
P. V. Novikov, O. R. Malyshev, K. A. Lyssenko, R. G. Kostyanovsky, “Resolution and racemization of nonbenzenoid atropenantiomers”, Mendeleev Commun., 14:6 (2004), 310–312
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc3923 https://www.mathnet.ru/rus/mendc/v14/i6/p310
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