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Эта публикация цитируется в 22 научных статьях (всего в 22 статьях)
Effect of spin density on the photochemical stability of aromatic nitrenes
S. V. Chapyshev
Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
Аннотация:
FTIR studies and UB3LYP/6-31G* calculations showed that triplet nitreno-1,3,5-triazines with zero-field splitting D-parameters of |D/hc| > 1.40 cm–1 and spin populations on the nitrene centres of ρN > 1.77 are photochemically very stable and do not rearrange into ring-expanded products on photolysis in cryogenic matrices.
Образец цитирования:
S. V. Chapyshev, “Effect of spin density on the photochemical stability of aromatic nitrenes”, Mendeleev Commun., 13:2 (2003), 53–55
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc3953 https://www.mathnet.ru/rus/mendc/v13/i2/p53
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