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Эта публикация цитируется в 10 научных статьях (всего в 10 статьях)
A stereochemical approach to the Kabachnik–Fields reaction mechanism
M. N. Dimukhametov, E. V. Bayandina, E. Yu. Davydova, A. T. Gubaidullin, V. A. Alfonsov
A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
Аннотация:
A comparison of the diastereomeric composition of Kabachnik–Fields reaction products with those of two reactions simulating its stereo-controlling steps showed that only the ‘imine’ mechanism works in the (MeO)2P(O)H–PhCHO-[(S),(R,S)-H2NCH(Ph)Me] system, like in the phosphite–imine system; in a similar system containing (R,S)-sec-butylamine, additional ‘nucleophilic amination’ of the initially formed α-hydroxybenzyl phosphonate occurs.
Образец цитирования:
M. N. Dimukhametov, E. V. Bayandina, E. Yu. Davydova, A. T. Gubaidullin, V. A. Alfonsov, “A stereochemical approach to the Kabachnik–Fields reaction mechanism”, Mendeleev Commun., 13:3 (2003), 150–151
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc3998 https://www.mathnet.ru/rus/mendc/v13/i3/p150
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