|
Reactions of chelated PtII and PtIII imidoimino complexes: N-nitrosation involving transfer of an NO group from inorganic nitrites and nitrates
M. O. Ponina, A. A. Sidorov, S. E. Nefedov, I. L. Eremenko, I. I. Moiseev
N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
Аннотация:
A bis-chelated imidoimino PtII complex, [(NPh)(N)C6H4]2Pt 1, was found to undergo N-nitrosation on reacting with AgNO2 or AgNO3 to form a product of formal HNO addition, [(NPh)(NNO)C6H4][(NPh)(NH)C6H4]Pt 3, that was characterised by X-ray analysis; similarly, an amidoimino binuclear PtIII complex was converted into 3 by reacting with NaNO2.
Образец цитирования:
M. O. Ponina, A. A. Sidorov, S. E. Nefedov, I. L. Eremenko, I. I. Moiseev, “Reactions of chelated PtII and PtIII imidoimino complexes: N-nitrosation involving transfer of an NO group from inorganic nitrites and nitrates”, Mendeleev Commun., 8:6 (1998), 207–208
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc4731 https://www.mathnet.ru/rus/mendc/v8/i6/p207
|
|
Обратная связь: