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Эта публикация цитируется в 4 научных статьях (всего в 4 статьях)
Mild alkane functionalisation leading to ethers: oxidative alkoxylation of cyclohexane with the dibromobis(phosphine)palladium(II)–sodium alkoxide system
A. N. Vedernikov, M. D. Sayakhov, B. N. Solomonov
Department of Chemistry, V.I. Ul'yanov-Lenin Kazan State University, Kazan, Russian Federation
Аннотация:
Dibromobis(phosphine)palladium(II) complexes, PdBr2(L)2 [L = PPh3, P(p-Tol)3], react with cyclohexane and an alcoholic solution of sodium alkoxide, NaOR (R = Me, Et, Pri), at 30–60°C affording the corresponding alkyl cyclohex-1-enyl ethers, ROC6H9, in 30–140% yield on palladium both under argon and under air; benzene is inert under the reaction conditions, sodium tert-butoxide does not enter the hydrocarbon alkoxylation.
Образец цитирования:
A. N. Vedernikov, M. D. Sayakhov, B. N. Solomonov, “Mild alkane functionalisation leading to ethers: oxidative alkoxylation of cyclohexane with the dibromobis(phosphine)palladium(II)–sodium alkoxide system”, Mendeleev Commun., 7:5 (1997), 205–206
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc4858 https://www.mathnet.ru/rus/mendc/v7/i5/p205
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