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Эта публикация цитируется в 16 научных статьях (всего в 16 статьях)
Carbonylation of Methylcyclopentane and Cyclohexane Initiated by the Aprotic Organic Superacid CBr4·2AIBr3
S. Z. Bernadyuk, I. S. Akhrem, M. E. Vol'pin
A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Аннотация:
The aprotic organic superacid CBr4·2AIBr3 initiates carbonylation of methylcyclopentane 1 and cyclohexane 2 with CO at atmospheric pressure with formation (after EtOH treatment) of various products in high yields depending on the conditions. The products are esters of 1-methylcyclopentanecarbonic (1a; at −45 °C) and cyclohexanecarbonic (2a; at 0°C) acids and 2-methylcyclohexanone (3; at − 23 °C); the reaction mechanism is discussed.
Образец цитирования:
S. Z. Bernadyuk, I. S. Akhrem, M. E. Vol'pin, “Carbonylation of Methylcyclopentane and Cyclohexane Initiated by the Aprotic Organic Superacid CBr4·2AIBr3”, Mendeleev Commun., 4:5 (1994), 183–185
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc5210 https://www.mathnet.ru/rus/mendc/v4/i5/p183
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