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Эта публикация цитируется в 45 научных статьях (всего в 45 статьях)
The First exo-nido-Ruthenacarborane Clusters. Synthesis and Molecular Structure of 5,6,10-[Cl(Ph3P)2Ru]-5,6,10-μ-(H)3-10-H-7,8-C2B9H8
I. T. Chizhevsky, I. A. Lobanova, V. I. Bregadze, P. V. Petrovskii, V. A. Antonovich, A. V. Polyakov, A. I. Yanovsky, Yu. T. Struchkov
A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Аннотация:
Novel exo-nido-ruthenacarboranes, 5,6,10-[CI(Ph3P)2Ru]-5,6,10-μ-(H)3-10-H-7,8-R2C2B9H6 (1; R = H, structurally characterized by an X-ray diffraction study, and 2; R = Me) have been prepared by reaction of RuCl2 (PPh3)3 and [nido-7,8-R2C2B9H10]− K+ in diethyl ether-tetrahydrofuran; in the solid state clusters 1 and 2 contain tridentate nido–carborane ligands bound to the RuII atom through three Ru—H—B bridging hydrogen bonds, whereas in solution they exist as an equilibrium mixture of isomeric exo-nido-bis(triphenylphosphine)chlorohydridoruthenacarboranes formed as a result of the cleavage of one of the Ru—H—B bonds with the formation of a new Ru—B σ-bond and a simultaneous hydrogen atom shift to the metal atom.
Образец цитирования:
I. T. Chizhevsky, I. A. Lobanova, V. I. Bregadze, P. V. Petrovskii, V. A. Antonovich, A. V. Polyakov, A. I. Yanovsky, Yu. T. Struchkov, “The First exo-nido-Ruthenacarborane Clusters. Synthesis and Molecular Structure of 5,6,10-[Cl(Ph3P)2Ru]-5,6,10-μ-(H)3-10-H-7,8-C2B9H8”, Mendeleev Commun., 1:2 (1991), 47–49
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc5488 https://www.mathnet.ru/rus/mendc/v1/i2/p47
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