Аннотация:
Gallium(III) catecholates with bipyridine ligand [(3,5-Cat)Ga(bipy)2]I and (3,6-Cat)GaI(bipy) (Cat is di-tert-butylcatecholate) were synthesized and characterized by single-crystal X-ray diffraction. The appearance of near-infrared ligand-to-ligand charge transfer for pentacoordinate complex was observed.
Образец цитирования:
A. V. Maleeva, I. V. Ershova, O. Yu. Trofimova, K. V. Arsenyeva, I. A. Yakushev, A. V. Piskunov, “Near-IR absorbing donor–acceptor charge-transfer gallium complex, an example from non-transition metal chemistry”, Mendeleev Commun., 32:1 (2022), 83–86