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Fizika i Tekhnika Poluprovodnikov, 2013, Volume 47, Issue 8, Pages 1022–1026 (Mi phts7981)  

This article is cited in 50 scientific papers (total in 50 papers)

Surface, interfaces, thin films

Study of the effect of the acid-base surface properties of ZnO, Fe$_2$O$_3$ and ZnFe$_2$O$_4$ oxides on their gas sensitivity to ethanol vapor

S. S. Karpovaa, V. A. Moshnikova, A. I. Maximova, S. V. Myakinb, N. E. Kazantsevac

a Saint Petersburg Electrotechnical University "LETI"
b State Technological Institute of St. Petersburg (Technical University)
c Tomas Bata University in Zlin, 760 01 Zlin, Czech Republic
Abstract: Binary (ZnO, Fe$_2$O$_3$) and ternary (ZnFe$_2$O$_4$) gas-sensitive oxide materials are synthesized, and the correlation between their sensitivity to ethanol vapor and the functional chemical composition of the surface is studied by X-ray photoelectron spectroscopy and by the technique of the adsorption of acid-base indicators. It is found that the sensitivity to ethanol increases with increasing content of Brönsted acid sites with the acidity index рK$_a\approx$ 2.5 and with increasing percentage of surface oxygen involved in OH/CO$_3$/C–O groups. This interrelation is attributed to the specific features of interaction between ethanol molecules and hydroxyl groups on the surface of the oxides.
Received: 03.12.2012
Accepted: 10.12.2012
English version:
Semiconductors, 2013, Volume 47, Issue 8, Pages 1026–1030
DOI: https://doi.org/10.1134/S1063782613080095
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: S. S. Karpova, V. A. Moshnikov, A. I. Maximov, S. V. Myakin, N. E. Kazantseva, “Study of the effect of the acid-base surface properties of ZnO, Fe$_2$O$_3$ and ZnFe$_2$O$_4$ oxides on their gas sensitivity to ethanol vapor”, Fizika i Tekhnika Poluprovodnikov, 47:8 (2013), 1022–1026; Semiconductors, 47:8 (2013), 1026–1030
Citation in format AMSBIB
\Bibitem{NalMosMax13}
\by S.~S.~Karpova, V.~A.~Moshnikov, A.~I.~Maximov, S.~V.~Myakin, N.~E.~Kazantseva
\paper Study of the effect of the acid-base surface properties of ZnO, Fe$_2$O$_3$ and ZnFe$_2$O$_4$ oxides on their gas sensitivity to ethanol vapor
\jour Fizika i Tekhnika Poluprovodnikov
\yr 2013
\vol 47
\issue 8
\pages 1022--1026
\mathnet{http://mi.mathnet.ru/phts7981}
\elib{https://elibrary.ru/item.asp?id=20319524}
\transl
\jour Semiconductors
\yr 2013
\vol 47
\issue 8
\pages 1026--1030
\crossref{https://doi.org/10.1134/S1063782613080095}
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  • https://www.mathnet.ru/eng/phts/v47/i8/p1022
  • This publication is cited in the following 50 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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